Tandem nucleophilic addition-Oppenauer oxidation of aromatic aldehydes to aryl ketones with triorganoaluminium reagents.

نویسندگان

  • Ying Fu
  • Yanshou Yang
  • Helmut M Hügel
  • Zhengyin Du
  • Kehu Wang
  • Danfeng Huang
  • Yulai Hu
چکیده

In the presence of pinacolone, the in situ prepared triorganoaluminium reagents reacted with aromatic aldehydes to give ketones in moderate to high yield. We propose that the products are formed via a tandem organoaluminium reagents addition-Oppenauer oxidation sequence.

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عنوان ژورنال:
  • Organic & biomolecular chemistry

دوره 11 27  شماره 

صفحات  -

تاریخ انتشار 2013